Atmospheric Carbon Dioxide Record from Mauna Loa
R.F. Keeling, S.C. Piper, A.F. Bollenbacher and J.S. Walker
Carbon Dioxide Research Group
Scripps Institution of Oceanography
University of California
La Jolla, California 92093-0444, U.S.A.
Period of Record
Air samples at Mauna Loa are collected continuously from air intakes at the top of four 7-m towers and one 27-m tower. Four air samples are collected each hour for the purpose of determining the CO2 concentration. Determinations of CO2 are made by using a Siemens Ultramat 3 nondispersive infrared gas analyzer with a water vapor freeze trap. This analyzer registers the concentration of CO2 in a stream of air flowing at ~0.5 L/min. Every 30 minutes, the flow is replaced by a stream of calibrating gas or "working reference gas". In December 1983, CO2-in-N2 calibration gases were replaced with the currently used CO2-in-air calibration gases. These calibration gases and other reference gases are compared periodically to determine the instrument sensitivity and to check for possible contamination in the air-handling system. These reference gases are themselves calibrated against specific standard gases whose CO2 concentrations are determined manometrically. Greater details about the sampling methods at Mauna Loa are given in Keeling et al. (1982) and Keeling et al. (2002).
Hourly averages of atmospheric CO2 concentration, wind speed, and wind direction are plotted as a basis for selecting data for further processing. Data are selected for periods of steady hourly data to within ~0.5 parts per million by volume (ppmv); at least six consecutive hours of steady data are required to form a daily average. Greater details about the data selection criteria used at Mauna Loa are given in Bacastow et al. (1985). Data are in terms of the Scripps "03A" calibration scale.
Mauna Loa, Hawaii, U.S.A.
Barren lava field of an active volcano
19°32' N, 155°35' W, 3397 m above MSL
The Mauna Loa atmospheric CO2 measurements constitute the longest continuous record of atmospheric CO2 concentrations available in the world. The Mauna Loa site is considered one of the most favorable locations for measuring undisturbed air because possible local influences of vegetation or human activities on atmospheric CO2 concentrations are minimal and any influences from volcanic vents may be excluded from the records. The methods and equipment used to obtain these measurements have remained essentially unchanged during the 51-year monitoring program.
Because of the favorable site location, continuous monitoring, and careful selection and scrutiny of the data, the Mauna Loa record is considered to be a precise record and a reliable indicator of the regional trend in the concentrations of atmospheric CO2 in the middle layers of the troposphere. On the basis of flask samples collected at Mauna Loa, and analyzed by SIO, the annual average of the fitted concentrations of CO2 rose from 315.98 ppmv in 1959 to 385.34 ppmv in 2008. This represents an average annual growth rate of 1.4 ppmv per year in the in situ values at Mauna Loa. For a summary of the flask samples at Mauna Loa and other sites, see http://cdiac.ornl.gov/trends/co2/sio-keel.html
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CITE AS: Keeling, R.F., S.C. Piper, A.F. Bollenbacher and J.S. Walker. 2009. Atmospheric CO2 records from sites in the SIO air sampling network. In Trends: A Compendium of Data on Global Change. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tenn., U.S.A. doi: 10.3334/CDIAC/atg.035