Summary of analytical techniques, PIs,
sample volumes, and shorebased analysis for TALK; PIs and analysis temperatures for fCO2
;PIs and sample volumes for pH analysis during the Pacific Ocean survey cruises.
| Section
|
TALK
Analysis Technique |
TALK P.I. |
Sample
Vol (mL) |
Shorebased
Std. Dev. (µmol/kg) |
n |
cfCO2
Analysis Technique |
fCO P.I.2 |
Analysis
Temperature (°C) |
eAnnotation |
pH
Analysis Technique |
pH P.I. |
Sample
Vol (mL) |
| P8S |
Potentiometric |
Shitashima |
50 |
4.3 |
17 |
NDa |
ND |
ND |
ND |
Potentiometric |
Shitashima |
30 |
| P9 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
| P10 |
Potentiometric |
Sabine |
100 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
| P13 |
Potentiometric |
Guenther/Keeling |
91 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
| P14N |
Potentiometric |
Millero |
200 |
ND |
ND |
ND |
ND |
ND |
ND |
Spectraphotomtric |
Winn |
30 |
| P14S15S |
Potentiometric |
Millero |
200 |
ND |
ND |
GC/Small |
Wanninkhof |
20 |
WG20 |
Spectraphotomtric |
Byrne |
10 |
| P15N |
Potentiometric |
Wong |
203 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
| EQS92 |
Potentiometric |
Millero |
200 |
ND |
ND |
IR |
Wanninkhof |
20 |
fWI20 |
Spectraphotomtric |
Byrne |
10 |
| P16C |
Potentiometric |
Guenther/Keeling |
91 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
| P16N |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
Spectraphotomtric |
Byrne |
10 |
| P16S17S |
Potentiometric |
Goyet |
100 |
3.2 |
12 |
GC/Large |
Takahashi |
20 |
T20 |
ND |
ND |
ND |
| P16A17A |
ND |
ND |
ND |
ND |
ND |
GC/Large |
Takahashi |
d>42.5S=4
<42.5S=20 |
T4/T20 |
ND |
ND |
ND |
| P17C |
Potentiometric |
Goyet |
100 |
9.0 |
24 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
| P17N |
bPotentiometric |
Goyet |
100 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
| CGC91 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
Spectraphotomtric |
Byrne |
10 |
| P17E19S |
ND |
ND |
ND |
ND |
ND |
GC/Large |
Takahashi |
4 |
T4 |
ND |
ND |
ND |
| P18 |
Potentiometric |
Millero |
200 |
ND |
ND |
IR |
Wanninkhof |
20 |
fWI20 |
Spectraphotomtric |
Byrne |
10 |
| P19C |
ND |
ND |
ND |
ND |
ND |
GC/Large |
Takahashi |
d>45.5S=4
<45.5S=20 |
T4/T20 |
ND |
ND |
ND |
| P2 |
bPotentiometric |
Ono |
150 |
ND |
ND |
ND |
ND |
ND |
ND |
Potentiometric |
Ono |
150 |
| P21 |
Potentiometric |
Millero |
200 |
ND |
ND |
ND |
ND |
ND |
ND |
Spectraphotomtric/ gPotentiometric |
Millero |
30 |
| P31 |
Potentiometric |
Winn |
200 |
ND |
ND |
ND |
ND |
ND |
ND |
Spectraphotomtric |
Winn |
30 |
| P6 |
ND |
ND |
ND |
ND |
ND |
GC |
ND |
ND |
ND |
ND |
ND |
ND |
| S4P |
ND |
ND |
ND |
ND |
ND |
GC/Large |
Takahashi |
4 |
T20 |
ND |
ND |
ND |
| SR3S4 |
Potentiometric |
Tilbrook |
210 |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
ND |
aND=No Data
bCRM's not analyzed
cIR=infrared analyzer with samples in 500ml volumetric flasks (Wanninkhof
and Thoning, 1993); GC/small=GC with 120ml bottles (Neill et al., 1996);
GC/large=GC with samples in 500ml volumetric flasks (Chipman et al.,
1993)dTemperature varied according to surface water temperature
eAnnotations used in Section 2.3
fSuspected to have anomalously low fCO2 at high fCO2
(= >700 µatm)
gEastern section of P21 analyzed using
potentiometric technique