******************************************************************* *** Atmospheric CO2 concentrations from Station "C" (ppmv) *** *** *** *** September 1994 *** *** *** *** Source: A.M. Brounshtein *** *** A.A. Shashkov *** *** N.N. Paramonova *** *** V.I. Privalov *** *** Y.A. Starodubtsev *** *** Main Geophysical Observatory *** *** Karbyshev Str. 7 *** *** 194018 St. Petersburg, Russia *** ******************************************************************* Year Jan. Feb. Mar. Apr. May Jun. Jul. Aug. Sep. Oct. Nov. Dec. Annual 1988 -99.99 -99.99 -99.99 360.1 357.3 352.3 345.8 344.3 349.4 352.2 356.2 360.2 -99.99 1989 361.8 360.8 362.5 359.9 357.6 352.5 345.8 345.2 345.2 352.7 355.6 358.3 354.8 1990 360.9 361.5 360.8 360.2 360.0 354.5 344.3 344.7 349.9 353.0 359.2 361.7 355.9 1991 361.9 361.3 366.2 362.7 360.7 356.4 350.2 348.8 350.8 356.6 361.4 362.4 358.3 1992 362.0 364.9 364.9 364.6 362.1 356.7 349.2 347.6 350.0 355.6 359.8 359.9 358.1 1993 361.9 362.5 361.1 363.4 361.0 357.2 350.0 347.3 351.2 358.2 363.1 367.7 358.7 Atmospheric CO2 concentrations are expressed in parts per million by volume (ppmv). Monthly averages are calculated from available individual flask measurements for a given month. Annual averages are based on monthly means. All flask measurements have been adjusted for concentration drift during storage time. The data scale presented here is based on initial manometric calibrations at the Scripps Institution of Oceanography (SIO) Central CO2 Laboratory in 1981 and on calibration experiments during 1990-93 against a set of CO2-in-air standards provided by the Atmospheric Environment Service (AES) of Canada. This scale is closely related to the SIO X87 mole fraction scale through AES standards. Note: None of the reference gases used by the Main Geophysical Observatory (MGO) has a CO2 concentration >355 ppmv. As a result, a linear extrapolation procedure has been applied to calculate concentration values for air samples with concentrations >355 ppmv up to mid-1992. Since August 1992, one of the AES calibration gases has been used along with the MGO reference gases to avoid extrapolation. The investigators estimate that the extrapolation error for measurements before 1992 does not exceed 0.15 ppmv.