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Date: Fri, 23 Apr 2004 16:05:57 -0700
From: Steve Emerson <emerson@u.washington.edu>
Subject: Re: Stud97
To: Robert Key <key@Princeton.EDU>
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References: <81C092BB-9493-11D8-84D5-000A959C6F86@noaa.gov>
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Hi Bob,
    I can answer some of your questions now and for some I'll have to do
some investigation.
    O2 values were mannually titrated by my technician Chuck Stump.
    CTD O2 data exists, but I think it is useless for anything quantitative
the reasons you mentioned.
    I  don't understand your question about pressure and depth.
    The Ship was the New Thompson; Cruise TTN-72
    I can't remember about pre and post cruise calibration.  I'll check with
the ship guys.
    We did and exhaustive calibration of the CTD salinity using Auto Sal
salinities and came to the conclusion that there should be no correction.
(The Auto Sal measurements were done by a student and didn't become real
high quality till near the end of the cruise.)
    Responsible person for the measurements.
    CTD, Emerson
    Nuts, Emerson
    O2, Emerson and Stump

    Regards, Steve


----- Original Message ----- 
From: "Robert Key" <key@Princeton.EDU>
To: "Marilyn Roberts" <marilyn.f.roberts@noaa.gov>
Cc: "Sabine Mecking" <smecking@whoi.edu>; "Steve Emerson"
<emerson@u.washington.edu>; "Paul Quay" <pdquay@u.washington.edu>
Sent: Friday, April 23, 2004 7:09 AM
Subject: Re: Stud97


> Marilyn, Sabine, Paul and Steve,
>
> Steve and Paul: This is the middle of a discussion which you may be
> able to add to regarding the STUD97 cruise.
> The "files" in question came to me from Marilyn (who got her copy from
> Paul) and from Sabine. I am trying to finish what has been started
> (merge, qc, submit to CDIAC, etc.). Sabine recommended I use CTD rather
> than bottle salinity, and I have done that.
>
> thx,
> bob
>
> I manually went through the ids in the STUD97 cruise file from
> Marilyn/Paul and corrected them to be unique. I then merged (as far as
> possible) with the vanilla data from the file from Sabine.
>
> Remaining questions/comments:
>
> 1. The  Marilyn/Paul file started at station 1. Sabine's  started at
> station 4. Does this imply that 1-3 were discarded as
> substandard/practice somewhere during processing?
>
> 2. There is a decided offset in the tco2 data relative to WOCE
> (P16N/P16C). The uniformity of the offset looks to me like a
> calibration problem rather than a "change". Based on an earlier message
> and the delta distribution these data have probably NOT been adjusted
> to CRM. Marilyn, if you have Winn's e-mail I can help follow up on this
> issue. Additionally, the following samples are a bit anomalous and need
> a close investigation. I do not recommend changing the flag values at
> this point:
> 8-1-12
> 16-1-24
> 18-1-19
> 20-1-9
>
> 3. I'd recommend flagging the following 3 alkalinity values with 3
> (station-cast-bottle)
> 10-1-13
> 12-2-13
> 14-1-14
> and take a close look at 26-1-12
>
> 4. Were the bottle oxygen values manually or automatically titrated? I
> don't normally pay attention to CTD oxygen values because of the known
> problems (hysteresis, calibration, spikes, etc.), but this is one case
> where a consistency check is probably justified. Does anyone have the
> CTD oxygen (if it exists)?
>
> 5. Pressure or Depth, chapter 2. The file Marilyn received from Chris
> Winn had sample location labeled as "desired pressure" which Marilyn
> truncated to "pressure" in her file with the merged carbon data. In
> Sabine's file it is labeled as depth which she confirmed was the listed
> label in the original file sent to her. The values in the two files are
> identical for a significant fraction (but not all) of the samples. The
> values are listed to a precision of Y.X which is consistent with
> pressure by WOCE standard (WOCE depths are integer). Hopefully Paul or
> Steve can resolve this issue.
>
> 6. Metadata details:
> Chief Scientist S. Emerson
> Ship Thompson ?
> Cruise number TT??? (not listed at the Thompson web site)
> Dates 11/1-23/1997
> Post-cruise CTD data calibration?
> Person/group responsible for:
> CTD (temperature, salinity, pressure) Emerson?
> nutrients ?
> oxygen ?
> carbon (C. Winn)
> other measurements if any ?
>
>

