ࡱ> !` 0bjbj\\ <>>(@@@@@@@T\"\"\"\"P#TT>h#:###*$ %')=:>:>:>:>:>:>$!@hB.^>@*% %**^>@@#*$s>E0E0E0*@#@*$=E0*=E0E0r;T@@;#@# KC| \"-Zm;=>0>{;2B.*B;;B@o<E0***^>^>#0"***>****TTTX TTTXTTT@@@@@@ Top of Form ( * =mandatory field) Investigator:*( - ) Name*: Dr. Christopher Sabine Organization: NOAA/PMEL Address: NOAA/PMEL 7600 Sand Point Way NE Seattle Washington, 98115 USA Phone: 206-526-4809 Email: chris.sabine@noaa.gov Dataset_Info:*( - ) Dataset_ID*: TAO140W_0_ Mar05_Sep05 Submission_Dates:*( - ) Initial_Submission: 20061117 (YYYYMMDD) Revised_Submission: (YYYYMMDD) Cruise_Info:*( - ) Experiment:( - ) Experiment_Name*: Cruise:( - ) Cruise_ID: (EXPOCODE) Section: (Leg) Geographical_Coverage:*( - ) Geographical_Region: Bounds:*( - ) 124.37W 0.18S Westernmost_Longitude: Enter decimal fractions of degrees: -139.90W (+ = E, - = W) or Degrees, Minutes, Seconds: Easternmost_Longitude: Enter decimal fractions of degrees: or Degrees, Minutes, Seconds: Northernmost_Latitude: Enter decimal fractions of degrees: 0 (+ = E, - = W) Southernmost_Latitude: Enter decimal fractions of degrees: Temporal_Coverage:( - ) Start_Date: 20050302 (YYYYMMDD) End_Date: 20050922 (YYYYMMDD) Vessel:*( - ) Vessel_Name: Vessel_ID: Country: Vessel_Owner: Platform Identifier: Mooring Mooring Location Longitude: Enter decimal fractions of degrees: -139.90W (+ = E, - = W) Latitude: Enter decimal fractions of degrees: 0 (+ = E, - = W) Start_Date: 20050302 (YYYYMMDD) End_Date: 20050922 (YYYYMMDD) Variables_Info:*( - ) Variable:( - ) Variable_Name*: (show pick list) Description_of_Variable: (E.g., in dry air) **General notes: - All measurements are at sea surface temperature and atmospheric pressure. - During the equilibration cycle, a closed loop of air equilibrates with seawater for 10 minutes. Once the equilibration period is complete, the pump stops and the system opens to the atmosphere allowing the pressure to equilibrate with atmospheric pressure. Measurements are recorded for 30 seconds at 2 hertz and then averaged. - During the air cycle, fresh air is pumped through the detector for 1 minute. Once the pump stops, the system opens to the atmosphere allowing the pressure to equilibrate with atmospheric pressure. Measurements are recorded for 30 seconds at 2 hertz and then averaged. - The gas streams for both the air cycle and equilibrator cycle are partially dried before entering the detector. The values listed as wet xCO2 generally have relative humidity levels ranging from 40 to 80 percent. The humidity levels increase over the course of a deployment. - Sampling occurs every 3 hours. The infrared detector is calibrated at the beginning of every sampling period. Averaged data and standard deviations for each measurement are transmitted back daily. - To calculate the dry measurements, the water mole fraction in the Licor detector must be known. A relative humidity sensor is located immediately downstream of the detector. - As a final step in the QC process, each data set is compared with the Marine Boundary Layer (MBL) data from GlobalView-CO2. The data from this deployment, March 2005 to September 2005, were within 0.1 umol/mol on average of the MBL data and therefore no correction was appliedumol/mol umol/mo. d. GLOBALVIEW-CO 2: Cooperative Atmospheric Data Integration Project - Carbon Dioxide. CD-ROM, NOAA CMDL, Boulder, Colorado [Also available on Internet via anonymous FTP to ftp.cmdl.noaa.gov, Path: ccg/co2/GLOBALVIEW], 2006 Measured Information: (Variable Name/Description) xCO2 SW (wet) (umol/mol) - Mole fraction of CO2 in air in equilibrium with the seawater at sea surface temperature and measured humidity. QF Quality Flag for xCO2 SW (wet). H2O (mmol/mol) - Mole fraction of H2O in air from equilibrator . xCO2 Air (wet) (umol/mol) - Mole fraction of CO2 in air from airblock, 4 feet above the sea surface at measured humidity. QF Quality Flag for xCO2 Air (wet) H2O (mmol/mol) - Mole fraction of H2O in air from airblock, 4 feet above the sea surface. Pressure of Licor (hPa) and Atm Atmospheric pressure at the airblock, 4 feet above the sea surface Licor Temp (C) Temperature of the Infrared Licor 820 in degrees Celsius % Saturation of O2 - The percent oxygen of the surface seawater divided by the percent oxygen of the atmosphere at 4 feet above the sea surface SST (C) - Sea Surface Temperature collected by NOAA/PMEL/TAO. Next Generation ATLAS sites provide internally recorded SST data at 10 minute resolution. The sea surface temperature collected during the equilibration period is reported in this dataset. The data presented here are not necessarily from the TAO finalized data set. The TAO Project Office advises to check the TAO site at the time of use for the most accurate data available. Salinity - Sea Surface Salinity collected by NOAA/PMEL/TAO. TAO records conductivity data at 10 minute intervals and then computes hourly averaged salinity during post-processing. The salinity reported during the equilibration period is reported in this dataset. The data presented here are not necessarily from the TAO finalized data set. The TAO Project Office advises to check the TAO site at the time of use for the most accurate data available. Derived Parameters: xCO2 SW (dry) (umol/mol) Mole fraction of CO2 in air in equilibrium with the seawater at sea surface temperature (dry air). xCO2 Air (dry) (umol/mol) Mole fraction of CO2 in air at the airblock, 4 feet above the sea surface (dry air). fCO2 SW (sat) uatm Fugacity of CO2 in air in equilibrium with the seawater at sea surface temperature (100% humidity). Since the measurements are taken at the sea surface, warming calculations are not necessary. fCO2 Air (sat) uatm Fugacity of CO2 in air at the airblock, 4 feet above the sea surface (100% humidity). dfCO2 Difference of the fugacity of the CO2 in seawater and the fugacity of the CO2 in air (fCO2 SW - fCO2 Air). Method_Description:*( - ) Equilibrator_Design:( - ) Equilibrator_Type: (show pick list) Bubble Equilibrator Equilibrator_Volume: (L) N/A Water_Flow_Rate: (L/min) N/A Headspace_Gas_Flow_Rate: (L/min) ~600 cc/min Vented: (show pick list) Yes Measurement_Method: Absolute, non-dispersive infrared (NDIR) gas analyzer Manufacturer_of_Calibration_Gas: NOAA CMDL (now Earth System Research Laboratory (ESRL) CO2_Sensors:( - ) CO2_Sensor:( - ) Manufacturer: Licor Model: Environmental_Control: LI-820 Resolution: 0.01 ppm Uncertainty: < 2.5% of reading with 14 cm bench (stated) <1.5 ppm determined in lab CO2_Sensor_Calibration: (For each calibration gas, document traceability to an internationally recognized scale, including date and place of last calibration. Include uncertainty of assigned value.) At the beginning of each sample, the instrument self-calibrates using a zero and high standard. The zero standard is generated by cycling a small amount of air through a soda lime chamber. The high standard is from a cylinder of calibrated standard reference gas, 514.54 umol/mol, from CMDL. CMDL standards are traceable to WMO x93 scale with a stated reproducibility of 0.06 micromole/mole. The standard used for this deployment was calibrated in July 2004. This cylinder is still in service and has not yet been post calibrated. Other_Sensors:( - ) Oxygen Sensor Manufacturer: Maxtec Model: Max-250 Resolution: 0.01 % Uncert-ainty: 2.0% Full Scale over operating temperature range 1.0% Full Scale @ constant temperature and pressure Calibration: (For each sensor of pressure, temperature, and salinity, document traceability to an internationally recognized scale, including date and place of last calibration.) Factory calibrated before purchase in June 2003. Recalibrated to sea level atmospheric air immediately before the deployment. Other_Sensors:( - ) Humidity Sensor Manufacturer: Sensirion Model: SHT71 Resolution: 0.01 % Uncertainty: Measurement range: 0-100% RH Absolute. RH accuracy: +/- 3% RH (20-80% RH) Repeatability RH: +/- 0.1% RH Calibration: (For each sensor of pressure, temperature, and salinity, document traceability to an internationally recognized scale, including date and place of last calibration.) Factory calibrated before purchase in June 2003. Method_References: (Publication(s) describing method) Sabine, C. (2005): High-resolution ocean and atmosphere pCO2 time-series measurements. The State of the Ocean and the Ocean Observing System for Climate, Annual Report, Fiscal Year 2004, NOAA/OGP/Office of Climate Observation, Section 3.32a, 246253. Data_set_References: (Publication(s) describing data set) None Citation: (How to cite this data set) Data_Set_Link:( - ) URL*:(m s t)HTMLCONTROL Forms.HTML:Text.1 \s Label*:(m s t)HTMLCONTROL Forms.HTML:Text.1 \s Link_Note: (Optional instructions or remarks)(m s t) HTMLCONTROL Forms.HTML:TextArea.1 \s Quality Flags definitions: 2 = Acceptable measurement; 3 = Questionable measurement; 4 = Bad measurement 5 = Not reported; 9 = Sample not drown for this measurement from this bottle. Quality Flag Log for this dataset. Date Measurement Value (Dry) Flag Comments 3/5/2005 6:17 xCO2_SW 478.1746696 3 cal error, probably 3 low 3/5/2005 6:17 xCO2_Air 376.9590239 3 cal error, probably 3 low 3/7/2005 3:17 xCO2_SW 483.1467357 3 cal error, probably 3 low 3/7/2005 3:17 xCO2_Air 377.0886234 3 cal error, probably 3 low 3/16/2005 6:17 xCO2_SW 546.7290542 4 cal error, ~53 ppm high 3/16/2005 6:17 xCO2_Air 432.0637852 4 cal error, ~53 ppm high 3/24/2005 3:17 xCO2_SW 418.9614043 4 cal error, ~50 ppm low 3/24/2005 3:17 xCO2_Air 329.0113559 4 cal error, ~50 ppm low 4/18/2005 12:17 xCO2_SW 415.2939114 4 cal error, ~50 ppm low 4/18/2005 12:17 xCO2_Air 328.2015626 4 cal error, ~50 ppm low 4/23/2005 21:17 xCO2_SW 560.6114504 4 cal error, ~53 ppm high 4/23/2005 21:17 xCO2_Air 432.2786228 4 cal error, ~53 ppm high 6/13/2005 6:17 xCO2_SW 557.4544707 4 cal error, ~53 ppm high 6/13/2005 6:17 xCO2_Air 433.5393919 4 cal error, ~53 ppm high 7/8/2005 0:17 xCO2_SW 496.1195159 3 cal error, may be 2 ppm low 7/8/2005 0:17 xCO2_Air 378.8490421 3 cal error, may be 2 ppm low 8/4/2005 9:17 xCO2_SW 488.854078 4 System appeared to stop and then restart, still settling 8/4/2005 9:17 xCO2_Air 372.8035007 4 System appeared to stop and then restart, still settling 9/4/2005 3:17 xCO2_SW 483.6328277 3 cal error, may be three ppm high 9/4/2005 3:17 xCO2_Air 382.4089488 3 cal error, may be three ppm high 8/9/2005 12:17 xCO2_Air 377.4 3 Cal error, may be 3 lowBottom of Form  "#/0125678<=?UWcenpwyzĞį~t~cUFh0Eh0UB*CJaJphh0UCJOJQJ^JaJ h0UhkyCJOJQJ^JaJh0Uhky5\!h0EhkyB*CJ^JaJphh0EhkyB*CJaJph hky5CJOJQJ\^JaJ)hky5B*CJOJQJ\^JaJph&h0Uhky5CJOJQJ\^JaJhky#hkyB*CJOJQJ^JaJphhkyCJOJQJ^JaJh2 #8Wpz % >  & Fdd[$\$gdky & Fdd[$\$gdP" & Fd\$gdYZ 8^8`gdYZ @&^gdH & Fd[$gd0U & Fdd[$\$gdky & FgdYZgdYZ&dPedgdky0     ͿͿ𸤿~~zi[OCOh\pB*CJaJphhiB*CJaJphhMCJOJQJ^JaJ h0UhkyCJOJQJ^JaJhky hky5CJOJQJ\^JaJ)hky5B*CJOJQJ\^JaJph&h0Uhky5CJOJQJ\^JaJ h0Uh0UhkyCJOJQJ^JaJ&hYZhky5CJOJQJ\^JaJh0EhYZB*CJaJphh0EhkyB*CJaJph        $ % 5 6 7 8 ; < > P S V ۵~mm\N?hHhI.B*CJaJphhI.CJOJQJ^JaJ h0UhkyCJOJQJ^JaJ hky5CJOJQJ\^JaJ)hky5B*CJOJQJ\^JaJphhkyCJOJQJ^JaJ&h0Uhky5CJOJQJ\^JaJh;WzhkyCJaJh0EhMB*CJaJphh\pB*CJaJphh YB*CJaJphhiB*CJaJphhKB*CJaJphV Z [ \ ] i {      ȺȺookoooooohky hky5CJOJQJ\^JaJ)hky5B*CJOJQJ\^JaJph&h0Uhky5CJOJQJ\^JaJ h0UhkyCJOJQJ^JaJhkyCJOJQJ^JaJhI.CJOJQJ^JaJ hI.hI.CJOJQJ^JaJh YB*CJaJphhHB*CJaJph*> i  * F  `  & Fdd[$\$gdky & Fdd[$\$gdky & Fdd[$\$gdI. & Fdd[$\$gdky & Fdd[$\$gdky & Fdd[$\$gdky & Fdd[$\$gdky ' ) * 0 1 2 3 6 7 8 E F [  ) M N O ӿ᪙yjYH!h0EhI.B*CJ^JaJph!h0EhkyB*CJ^JaJphh\ph\pB*CJaJphh0EhI.B*CJaJph hI.hI.CJOJQJ^JaJ hky5CJOJQJ\^JaJ)hky5B*CJOJQJ\^JaJph&h0Uhky5CJOJQJ\^JaJhI.CJOJQJ^JaJhkyCJOJQJ^JaJ h0UhkyCJOJQJ^JaJO P Q _ ` u ɸɤɓɸvjɸv^jɤI)hky5B*CJOJQJ\^JaJphhiB*CJaJphh YB*CJaJphh0EhI.B*CJaJphhI.CJOJQJ^JaJ hky5CJOJQJ\^JaJ&h0Uhky5CJOJQJ\^JaJ h0UhkyCJOJQJ^JaJhkyCJOJQJ^JaJhCJOJQJ^JaJhCCJOJQJ^JaJh\pB*CJaJph    & 4 Q c  6 7 O _ ^gdY & Fdd[$\$gdkygdD,gdP"gd$ & Fdd[$\$gd6 & Fdd[$\$gdky & Fdd[$\$gdky & Fdd[$\$gdky        $ & 2 3 4 b ͼͼͼͼͮrcWcFrW!h0EhP"B*CJ^JaJphh\pB*CJaJphh0EhP"B*CJaJph#hB*CJOJQJ^JaJph)hP"hP"B*CJOJQJ^JaJph)hP"h6B*CJOJQJ^JaJphh6CJOJQJ^JaJ h0UhkyCJOJQJ^JaJhkyCJOJQJ^JaJ&h0Uhky5CJOJQJ\^JaJ hky5CJOJQJ\^JaJ      ! 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