Index of /ftp/oceans/CARINA/Meteor/06MT592
Please cite this data set as:
Wallace, D. and M. Rhein. 2007. Meteor 06MT20030723 (SFB 460) cruise data from the
2003 cruises, CARINA Data Set. http://cdiac.ornl.gov/ftp/oceans/CARINA/Meteor/06MT592/.
Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, US Department
of Energy, Oak Ridge, Tennessee. doi: 10.3334/CDIAC/otg.CARINA_06MT20030723
# 11/21/07 Initialized README file
# Data from T.Tanhua (12/20/06) and R.Steinfeldt (12/15/06)
# Ship: Meteor
# Cruise: 59/2; Experiment SFB 460
# Dates: 7/23-8/29/2003
# EXPOCODE: 06MT20030723
# Region: Subpolar North Atlantic: Reykjavik, Iceland to St. Johns, Canada
# Ch. Sci. Monika Rhein; Univ. Bremen, Inst. .Env. Phys., Dpt Oceanogr.
# 131 stations; 24 place Rosette
# Hydro: Who - M. Rhein; Status - final
# Notes: Updated values from R.Steinfeldt 1/23/08
# ea-Bird 911 plus
# Temperature (ITS-90), accuracy 0.003C
# Salinity (PSS-78), accuracy 0.003
# Bottle salinity: measured with Guildline Autosal 8400 A,
# precision 0.001; standard seawater: batches P139 and P141
# See Kieke et al. 2007
# Nuts/O2: Who - F. Malien; Status - final
# Notes: Oxygen by Winkler titration. Precision estimate from replicates (95 % confidence interval) +/- 0.51 umol/kg.
# Nutrients: Precision about 1%. Precision from duplicates:
# 0.205 +/- 0.09 umol/kg for NO3,
# 0.005 umol/kg for NO2,
# 0.025 +/- 0.013 umol/kg for PO4,
# 0.5 +/- 0.06 umol/kg for SiO2.
# TCO2: Who - T. Tanhua; Status - final
# Notes: Coulometric titration [Johnson et al., 1993].
# CRM corrected from 3 batches (batch # 56, 58 and 60). Mean offset was 0.02 +/- 1.48 umol/kg (95% confidence interval, n = 129).
# Precision of the measurements was 1.2 umol/kg (95% confidence interval), as determined from analyses of 120 duplicate samples.
# TA: Who - ; Status - final
# Notes: Potentiometric titration [Mintrop et al., 2000].
# CRM corrected from 4 batches (batch # 56, 58 and 60). Mean difference was 0.02 +/- 1.93 umol kg-1 (n=116).
# Precision 2.3 umol kg-1, determined from measurements of 119 duplicate samples, but general scatter of ~5umol/kg. Difficult to QC.
# pH: Who - ; Status - final
# Notes: Spectrophotometric method (DOE, 1994), Originally reported on total H scale @ 21.0C.
# Precision +/- 0.002 pH units. A drift in the response to CRMs was corrected.
# Converted to SWS@25C
# CFC: Who - M. Rhein; Status - final
# Notes: Updated values from R.Steinfeldt 1/23/08
# CFC-11: SIO-93 scale, accuracy 6%, minimum error 0.06 pmol/kg
# (calibration problems, all data flagged 3)
# CFC-12: SIO-93 scale, accuracy 1.5%, minimum error 0.03 pmol/kg
# See Rhein et al. 2007.
# Converted to SIO-98 scale 11/21/08
# References:
# DOE, 1994. Handbook of methods for the analysis of various parameters of the carbon dioxide system in sea water.
ORNL/CDIAC-74, U. S. Dep. of Energy, Oak Ridge Natl. Lab., Oak Ridge, Tenn., USA.
# JOHNSON, K.M., WILLS, K.D., BUTLER, D.B., JOHNSON, W.K. UND WONG, C.S., 1993. Coulometric total carbon dioxide
analysis for marine studies: Maximizing the performance of an automated gas extraction system and coulometric
detector. Mar. Chem., 44(2-4): 167-188.
# Kieke, D., et al. (2007). Changes in the pool of Labrador Sea Water in the subpolar North Atlantic. Geophys.
Res. Lett. 34, L06605, doi: 1029/2006GL028959.
# MINTROP, L., PEREZ, F.F., GONZALEZ-DAVILA, M., SANTANA-CASIANO, J.M. UND KORTZINGER, A., 2000. Alkalinity
determination by potentiometry: intercalibration using three different methods. Ciencias Marinas, 26(1): 23-37.
# Rhein, M., D. Kieke, and R. Steinfeldt (2007). Ventilation of Upper Labrador
# Sea Water, 2003-2005. Geophys. Res. Lett., 34, L06603, doi:10.1029/2006GL028540.