Index of /ftp/oceans/CARINA/Hesperides/HE091

Icon  Name                           Last modified      Size  Description
[DIR] Parent Directory                                    -   
[   ] 29HE20030408.exc.csv           18-Dec-2008 09:49   33K  
[TXT] Cruise-Ficaram6.doc            09-Apr-2007 08:22   39K  

Please, site these data set as:

Rios, Aida F. and Fiz F. Perez 2004. Carbon Data Obtained During the R/V  Hesperides Cruise in the Atlantic Ocean on 
CLIVAR Repeat Hydrography Sections FICARAM VI, (8 - 24 April, 2003). http://cdiac.ornl.gov/ftp/oceans/CARINA/Hesperides/HE091/. 
Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, US Department of Energy, Oak Ridge, Tennessee.   

# This file initialized 4/6/07 
# Data from Rios 4/9/07 and 4/9/07 
# Ship: Hesperides 
# Cruise: 29HE091, FICARAM VI 
# Dates: 4/8-4/24/2003 
# EXPOCODE: 29HE20030408 
# Region: ~24N, very sparse section from 65W to 20W then to Gibralter 
# Chief Scientist: A. Rios 
# 7 full depth stations;  with 24 place Rosette 
# Hydro: Who - A. Rios; Status - final 
# 	Notes: 	 
# Nuts/O2: Who - C.Castro; Status - final  
# 	Notes: estimated O2 error of +/-1umol/kg 
# 	Nutrients frozen prior to analysis. Estimated errors: 
# 		+/-0.05 umol/kg for nitrate 
# 		+/-0.05 umol/kg for silicic acid 
# 		+/-0.01 umol/kg for phosphate 
# 	Methods see: Hansen and Grasshoff (1983), 
# 		Mourino and Fraga, 1985; Alvarez-Salgado et al., 1992 
# TCO2: Who - R. Wanninkhof; Status - final 
# 	Notes: file only has a few samples measured ashore for check 
# TA: Who - A. Rios; Status - final 
# 	Notes: potentiometric titrations with hydrochloric acid to 
# 		a final pH of 4.40 (Perez and Fraga, 1987).  
# 		The electrodes were standardised using a buffer of  
# 		pH 4.42 made in CO2 free seawater (Perez et al., 2000) 
# 	CRM batch 54 analysis implied uncertainty of +/-0.7 umol kg-1 
# fCO2: Who - A. Rios; Status - final 
# 	Notes: surface water only 
# pH: Who - A. Rios; Status - final; S Plus -  up to date 
# 	Notes: SWS@25C 
# 	spectrophotometrically following Clayton and Byrne (1993) 
# 	CRM batch 54 analysis implied uncertainty of 0.0002 
# References: 
# Alvarez-Salgado X.A., F. Fraga and F.F. Perez, 1992: Determination of nutrient salts by automatic methods both in 
seawater and brackish waters: The phosphate blank. Marine Chemistry, 39, 311-319. 

# Clayton, T.D., R.H. Byrne. 1993. Spectrophotometric seawater pH measurements: total hydrogen ion concentration scale 
concentration scale calibration of m-cresol purple and at-sea results. Deep-Sea Res. I, Vol. 40, 10, 2115-2129. 

# Hansen, H.P. and Grasshoff, K. Automated Chemical Analysis. In: K. Grasshoff, M. Ehrhardt and K. Kremlig (Editors), 
Methods of Seawater Analysis. Verlag Chemie, Weinheim, 419 pp., 1983. 

# Lueker, T.J., Dickson, A.G., Keeling, C.D., 2000. Ocean pCO2 calculated from dissolved inorganic carbon, alkalinity 
and equations for K1 and K2: validations based on laboratory measurements of CO2 in gas and seawater at equilibrium. Mar. Chem., 70, 105-119. 

# Mourino C., F. Fraga, 1985: Determinacion de nitratos en agua de mar. Investigacion Pesquera, 49, 81-96. 

# Perez, F.F., Fraga, F., 1987. A precise and rapid analytical procedure for alkalinity determination. Marine Chemistry, 21, 169-182.
 
# Perez, F.F., A.F. Rios, T. Rellan, M. �lvarez. 2000. Improvements in a fast potentiometric seawater alkalinity determination. Ciencias Marinas, 26, 463-478.